应用
Poly(methylhydrosiloxane) is used in the reduction of esters to alcohols, catalyzed by a combination of titanocene dichloride and either n-BuLi or EtMgBr. It is a safer alternative to triethoxysilane, B22063, for reduction of phosphine oxides to phosphines, catalyzed by Ti(O-i-Pr)4. It is also used in greener amine synthesis by reductive amination as an alternative to borohydrides.
备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Incompatible with strong oxidizing agents, amines and bases.
基本信息
MDL
MFCD00084478
分子式
(CH3)3SiO[(CH3)HSiO]nSi(CH3)
分子量
ca 1900
闪点
204°(399°F)
密度
1.006
折射率
1.3980
灵敏度
Ambient temperatures.
形态
Liquid
溶解性
Not miscible or difficult to mix in water.
安全信息
TSCA
是
阿法埃莎