应用
Palladium(II) trifluoroacetate is used in the preparation of allyl-palladium complexes. It acts as a catalyst used in the mild decarboxylation of electron-rich aromatic acids and the direct cross-coupling of unactivated arenes. Further, it is involved in the selective allylic oxidation of geranylacetone and other olefins to their allyl acetates in order to prepare keto alcohols.

备注
Stable. Store in a tightly closed container. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00013204

分子式
Pd(O₂CCF₃)₂

分子量
332.44

熔点
210° dec.

灵敏度
Hygroscopic. Ambient temperatures.

形态
Powder

溶解性
Soluble in diethyl ether and acetone. Insoluble in benzene, chloroform and trifluoroacetic acid.

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否