应用
Indium(III) chloride hydrate is used for mild and selective cleavage of tert-butyldimethylsilyl ethers. It is a Lewis acid, and serves as a catalyst for many organic transformations. It also catalyzes the conversion of aldehydes to gem diacetates by chemoselective process. Lithium indium hydride, an in situ reducing agent, can be prepared from indium trichloride. It catalyzes reactions such as Friedel-Crafts acylations and Diels-Alder reactions. It also catalyzes Knoevenagel condensation between the barbituric acid and the aldehyde.
备注
Keep away from strong bases and strong oxidizing agents.
基本信息
MDL
MFCD00011058
EINECS
233-043-0
分子式
InCl3?xH2O
分子量
221.18(anhy)
灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.
形态
Crystalline
溶解性
Soluble in water, diethyl ether, and THF.
Merck
14,4958
GHS危害和防范说明
GHS符号
Hazard Statements
H302-H314-H318
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.
Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险等级
8
包装组
II
危险类别
22-34
Harmful if swallowed.Causes burns.
安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste
欧盟危险品标志
TSCA
是