应用
A H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).

备注
Incompatible with strong oxidizing agents. Solutions undergo decomposition at high temperatures.

基本信息

MDL
MFCD00011209

EINECS
239-287-4

分子式
C₁₂O₁₂Ru₃

分子量
639.33

熔点
ca 150° dec.

灵敏度
Ambient temperatures.

形态
Crystalline

溶解性
Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone.

GHS危害和防范说明

GHS符号

Hazard Statements
H331
Toxic if inhaled.

Precautionary Statements
P261-P304+P340-P311a-P405-P403+P233-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Store in a well-ventilated place. Keep container tightly closed.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
23
Toxic by inhalation.

安全等级
9-36-45-60
Keep container in a well-ventilated place.Wear suitable protective clothing.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

TSCA
是