应用
(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.

备注
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00009143

EINECS
201-783-3

分子式
C₈H₁₄O₆

分子量
206.19

熔点
17°

沸点
280°

闪点
93°(199°F)

密度
1.205

折射率
1.4460

灵敏度
Ambient temperatures.

形态
Viscous liquid

溶解性
Fully miscible in water.

Beilstein
1727145

Merck
14,3855

GHS危害和防范说明

Hazard Statements
H227
Combustible liquid.

Precautionary Statements
P210e-P280a-P370+P378a-P403+P235-P501a
Wear protective gloves and eye/face protection.In case of fire: Use for extinction: CO2, powder or water spray.Store in a well-ventilated place. Keep cool.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

安全等级
15
Keep away from heat.

TSCA
是