应用
Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.

备注
Air sensitive. Hygroscopic. Incompatible with strong acids and strong oxidizing agents.

基本信息

MDL
MFCD00149634

EINECS
606-073-0

分子式
CeCl₃?7H₂O

分子量
372.60 (246.48anhy)

灵敏度
Hygroscopic. Air Sensitive. Store under Argon. Ambient temperatures.

形态
Crystals

溶解性
Soluble in alcohol, water, and acetone. Slightly soluble in tetrahydrofuran.

Merck
14,1997

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H315-H319-H335
May be harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

RTECS
FK5100000

TSCA
是