应用
2-Bromopyrimidine is used in the preparation of 2,7-bis(2-pyrimidyl)-9,9-dihexylfluorene by cross-coupling with 9,9-dihexylfluorene-2,7-diboronic acid. It undergoes microwave-assisted aminocarbonylation at C-2 with palladium and molybdenum hexacarbonyl.

备注
Store in a cool place. Incompatible with strong oxidizing agents, strong acids, acid chlorides.

基本信息

MDL
MFCD00014601

EINECS
224-993-7

分子式
C₄H₃BrN₂

分子量
158.99

熔点
53-57°

沸点
62-64°/1.5mm

灵敏度
Keep Cold.

形态
Crystalline powder

溶解性
Miscible with water.

Beilstein
605945

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
是