应用
Aluminum tert-butoxide is utilized as a reagent in the Oppenauer oxidation of alcohols to ketones. It is also used in Meerwein-Ponndorf-Verley reduction of ketones. It is actively involved in the preparation of 1,1,2-triethoxyethene by reacting with 1,1,2,2-tetraethoxyethane followed by the elimination of alcohol.

备注
Air and moisture sensitive. Incompatible with acids. Conditions to avoid heat, flames and sparks. Extremes of temperature and direct sunlight.

基本信息

MDL
MFCD00008801

EINECS
209-146-1

分子式
Al[OC(CH₃)₃]₃

分子量
246.32

熔点
200-202°

沸点
156°/2mm

密度
1.025

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Powder

溶解性
Very soluble in organic solvents like alcohols, benzene, toluene and xylene.

Beilstein
4148229

Merck
14,333

GHS危害和防范说明

GHS符号

Hazard Statements
H228-H314-H318
Flammable solid.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Keep away from heat/sparks/open flames/hot surfaces. - No smoking.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
4.1

包装组
III

危险类别
11-34
Highly flammable.Causes burns.

安全等级
16-26-36/37/39-45
Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA
是