应用
Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.

备注
Store in cool place. Incompatible with strong oxidizing agents and acids.

基本信息

MDL
MFCD00008635

EINECS
212-104-5

分子式
CH₂=CHCH₂Si(CH₃)₃

分子量
114.27

沸点
85-86°

闪点
-10°(14°F)

密度
0.717

折射率
1.4080

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with organic solvents. Immiscible with water.

Beilstein
906755

GHS危害和防范说明

GHS符号

Hazard Statements
H225-H315-H319-H335
Highly flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
II

危险类别
11-36/37/38
Highly flammable.Irritating to eyes, respiratory system and skin.

安全等级
9-16-23-26-33-37
Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges.

欧盟危险品标志

TSCA
是