应用
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) is used in many asymmetric catalysis applications, glove box and Schlenk techniques should be employed to prevent exposure of the rare earth catalyst to air and moisture, which can be detrimental to the reaction outcome.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Never allow product to get in contact with water during storage. Over time, pressure may increase causing containers to burst Handle and open container with care. Air, Moisture sensitive. Reacts violently with water. Keep away from strong oxidizing agents.

基本信息

MDL
MFCD03427091

分子式
C₁₈H₅₄GdN₃Si₆

分子量
638.41

熔点
161-167°

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Powder

溶解性
Soluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H228-H261-H314-H318
Flammable solid.In contact with water releases flammable gas.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210-P280-P305+P351+P338-P309-P310-P402+P404
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.Store in a dry place. Store in a closed container.

安全信息

危险等级
4.3

包装组
II

危险类别
11-14/15-34
Highly flammable.Reacts violently with water, liberating extremely flammable gases.Causes burns.

安全等级
7/8-16-26-36/37/39-43-45
Keep container tightly closed and dry.Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of fire, use ... (indicate in the space the precise type of fire fighting equipment. If water increases risk, odd 'Never use water')In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA
否