应用
Triphenylphosphine sulfide involves in the , conversion of epoxides to episulfides (thiiranes) in presence of TFA of the same stereochemistry. It acts as a ligand for the Pd-catalyzed bisalkoxycarbonylation of olefins.

备注
Store in a cool, dry, conditions in well sealed container. Store away from oxidizing agents.

基本信息

MDL
MFCD00004917

EINECS
223-407-7

分子式
C₁₈H₁₅PS

分子量
294.36

熔点
158-164°

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Insoluble in water.

Beilstein
645872

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H331-H315-H319-H335
Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
20/21/22-36/37/38
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

RTECS
SZ2820000

TSCA
否